Out of many ways to divide document into sections, you can simply make use of Word 2010 build-in horizontal line option to insert a divider.
For inserting horizontal line, place the insert cursor where you want to insert it and head over Home tab, from Paragraph group, click drop-down button and select Horizontal Line as shown below.

It will quickly insert a horizontal line in the document.

From the menu shown above, you can also box up any part of document by Outside Borders, use Inside Vertical & Horizontal Border, insert Diagonal Up Border, etc.
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